Having never bought aquarium salts I can't tell you the differences. Some people like to use a little salt in their aquariums as a 'tonic' for the fish. Some fish prefer it. Mollies like a bit of salt and some livebearer breeders swear by it. Whether this is the same salt used in marine tanks I don't know, as I don't keep marines, but I doubt it.
When I kept mollies, I just used plain table salt (non iodised). The amount used is very small (can't remember how much exactly. Check out 'How to Salt a Freshwater Aquarium' in the beginner section) as it was discussed there.
Brackish tanks have a salinity halfway between fresh and marine. This is to simulate regions where fish live in the tidal areas of rivers where they meet the sea so salinity changes as the tide goes in and out.