For now I have scooped off a few litres from my 80L bug-quarium that was overflowing in the rain.
From the tap it's 4 drops or 71.6 ppm to turn yellow, in the cory/loach tank it's 7 drops or 125.3 ppm.
I see that the buffering is useful, but if I have a regular feeding and water change regime, and normally good water parameters, where would a pH spike come from?