Yeah, noone has ever successfully used concrete in a fish tank, it might be full of scary chemicals.
BTW, cement is what holds the concrete together, you don't use it alone.
Below successful examples, and instructions:
http://www.garf.org/class.html
http://www.fnzas.org.nz/fishroom/viewtopic.php?f=28&t=58285&hilit=concrete+back+background
http://www.fnzas.org.nz/fishroom/viewtopic.php?f=10&t=58184&hilit=concrete+back+background
http://www.cichlid-forum.com/articles/diy_aquarium_background.php
http://www.aquariumadvice.com/forums/f20/concrete-background-26290.html
http://www.reefcentral.com/forums/showthread.php?t=2037046