I agree that smaller water volumes pass through skimmers more often, therefore have a better chance of clenaing, however...
The concentration of the nutrients in the water column of the larger system will be more spread out than the smaller system therefore the inhabitants of the system will only come into half as much contact as the smaller system.
The skimmer in the larger system will still get skimmed just as efficiently because you have obviously added a larger skimmer.
Dont forget this....
I agree with the skimmer statements Layton, but thats not what this is about.
Look at it this way:
Two tanks...
1: 1000 litres with 100kg LR, 20 corals and 20 fish, small skimmer.
2: 2000 litres with 100kg LR, 20 corals and 20 fish, larger skimmer.
Tank 1 will have the same nutrient levels as tank 2 due to the waste load produced by the inhabitants and LR, (This a set measurement), however these nutrients are spread out throughout the larger water column and are diluted. The bigger skimmer will pull these out just as fast as the smaller tank and skimmer, as it is rated for more literage.
Similar to the air at sea level in contrast to the top of Mt Everest where the air is almost zero.