phosphate and nutrients/nitrates can only leave a zeo tank a few ways
1) water changes, but at the low levels done i do not think it would lower levels like people say
2) skimmate, but unless something makes the organics more skimmable, which you should be able to "see" in the skimate"
3) in the rocks when you change them....
is the phosphate binding with the al in the rocks, and in the bacterial process that does this, nitrate is used up?????