I am a glass merchant
Through the glass merchant supplies, there is not ONE silicone that is made food safe and that is what you are talking about. The tests needed to garentee food safe product cost thousands of dollars and the market is far too small to bother spending that amount of money on.
In saying that, silicone is not an adhesive (glue) but we use it for that as well without any problems
I use Dow Coring 580 clear and Dow Coring 480 black for my tanks and have had no problems.
The person behind the counter of the department stores has no "indepth" knowledge but has an overview on most things but still relies on packageing and suppliers back up for more indepth information
If glueing rocks together I would tend to read the lable and see what is OK from tiles and the like, glue them together then soak them for a few days changeing the waters a couple of times of if possible put in a fish to make sure that no leaching has occured