Most log fires can barely do 74% efficiency, and the clean air regulations now require combustion to be at least 65% efficient.
I've come across something called a rocket mass heater which uses small amounts of wood, and is very efficient .. probably similar to a pellet stove. The emissions are said to be only CO2 and water. You can choose to use them for heating, or cooking. Not really both as the design is slightly different. The rocket mass heater achieves its efficiency using a tall chimney, and hotter temperatures so that all the gases are combusted as well. All the gas is then passed horizontally thru a large thermal mass which then continues to radiate heat many hours after the fire has extinguished. So, similar to a Kang except the Kang takes the exhausts directly from the furnace rather after a secondary combustion chamber. Not sure if one built one here whether one could get the rocket mass heater permitted.
There's a video from the local permaculture guys showing how to built a rocket heater ( for cooking ) using 5 cinder blocks. Probably not suitable as cinder blocks would likely crumble eventually under the heat. And there's a video on youtube showing how to build one using 16 (I think) chimney bricks.
I removed my chimney in my renovations, and now wonder if I should have left it there, and converted the fireplace to a rocket heater!