Generally yes. If you KH is in normal ranges, your pH will be fine.
The one thing which affects the relationship between KH and pH is CO2.
For example, if you have a buildup of CO2 around your tank, then although your KH may be fine, you may find that pH is lower than normal.
Or if you run a calcium reactor, you may find that pH is lower than it otherwise would be because of excess CO2.
I haven't tested pH in years. KH is far more important.
Baking soda temporarily lowers pH (while the carbonate / bicarbonate equilibrium establishes itself)
Baked Baking soda when added to salt water results in a pH of around 8.3, so it shouldn't raise pH (unless pH is low already)
Honestly it's not really worth watching pH when adding baking soda, or baked baking soda, in small amounts.
If you're adding a LOT of baking soda then, maybe yes, but it's only a temporary effect.
Layton