Since when have I ever needed an invitation to say what I want
Ca and Alk are indirectly related through pH. Then magnesium and clacium are more closely related.
Calcium is supersaturated in seawater, ready for precipitation at any small trigger. Magnesium helps prevent this precipitation by poisioning crystals of calcium carbonate to prevent runaway precipitation (or the snow storm effect)
Magnesium should be 3 times the calcium level. The lower it is, the easier it is for calcium levels to drop through precipitation.
pH also effect the solubility of calcium in seawater, which is linked to alkalinity in that the lower the alkalinity, the easier it is for the pH to change.
Then if calcium is dropping through low calcium, it also drags down alkalinity, which makes it easier for changes in pH to occur, which just increases the precipitation of calcium out of the water. This sort of positive feedback is something to avoid!
The interactions between these parameters are relatively complex. I wouldn't want to be doing any sort of quantitative analysis on it!
As for how quickly you can change alkalinity, well at one point I was increasing it in one go by 2-3 dkH daily. The biggest I changed was
4 dkH in a day.
I noticed at around 5 and 6dKH corals were severely affected.
Layton