It won't help. The phosphate has to be in the water to work.
The thing is that if it had been sitting on the rock for a while then the rock can absorb the nutrients.
Then it takes time for bacteria to migrate this out of the rock again. But for this to happen, the rock surface has to be kept clear of detritus, and water has to be kept clean.
I'm not suggesting ripping the tank apart. Just pay careful attention to the spots where this stuff is, and blow them out with a powerhead regularly, until they clear up.
Layton